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Title: | NHC catalyzed transformation of aromatic aldehydes to acids by carbon dioxide: An unexpected reaction |
Authors: | Vijay Nair, G Vimal Varghese Paul, R R Anu, J Sinu, C R Rajeev S Menon |
Keywords: | N-heterocyclic carbenes Multicomponent reactions Gamma-butyrolactones Direct annulations Carboxylic-acids Stetter reaction Ionic liquids CO2 Fixation Enals Organocatalysts |
Issue Date: | 2010 |
Publisher: | American Chemical Society |
Citation: | Organic Letters 12(11):2653-2655;04 Jun 2010 |
Abstract: | A facile NHC-mediated reaction of aromatic aldehydes with carbon dioxide leading to carboxylic acids is described. The present protocol is mechanistically important, and it can serve as a tool for the sequestration of carbon dioxide. |
URI: | http://ir.niist.res.in:8080/jspui/handle/123456789/1002 |
ISSN: | 1523-7060 |
Appears in Collections: | 2010 |
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