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Please use this identifier to cite or link to this item: http://localhost:8080/xmlui/handle/123456789/1240
Title: Novel nucleophilic heterocyclic carbene mediated stereoselective conjugate addition of enals to nitrostyrenes via homoenolate
Authors: Vijay Nair, G
Sinu, C R
Beneesh, P B
Varghese, V
Anu Jose
Suresh, E
Keywords: Bond forming reactions
Gamma butyrolactones
Michael additions
Enantioselective synthesis
Carbonyl compounds
Silyl ether
Nitroalkenes
Issue Date: 2009
Publisher: American Chemical Society
Citation: Organic Letters 11(24):5570-5573;17 Dec 2009
Abstract: A stereoselective Michael addition of homoenolate, generated from enals by nucleophilic heterocyclic carbene (NHC) catalysis, to beta-nitrostyrenes is reported for the first time. The products of this reaction obtained in good yields are of potential value in the synthesis of a variety of acyclic and heterocyclic compounds.
URI: http://ir.niist.res.in:8080/jspui/handle/123456789/1240
ISSN: 1523-7060
Appears in Collections:2009

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