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Title: | Formation of novel polycyclic cage compounds through 'uncaging' of readily accessible higher cage compounds |
Authors: | Beena James Rath, N P Suresh, E Mangalam S Nair |
Keywords: | Cyclization Polycyclic cage compounds |
Issue Date: | 2006 |
Publisher: | Elsevier |
Citation: | Tetrahedron Letters 47(32):5775-5779;7 Aug 2006 |
Abstract: | The synthesis of the novel cage compounds 7-halomethyl-8-(carbomethoxy)tetracyclo[4.2.1.1(4,7).0(2,5)]deca-3-(11)-ene-10-ones, methyl-4-methylene-6-oxopentacyclo[5.4.0.0.(2,5).0(3,10).0(7,9)]undecane-9-carboxylate, 3-chloromethyl-4-(carbomethoxy)tetracyclo[4.2.1.1.(3,8).0(2,5)]deca-7(11)ene-10-one, 2-bromo-5-methyl-8-methylene-6-oxotricyclo[5.3.0.0(3,9)]decane-4-carboxylic acid and 2-bromo-5-methyl-8-methylene- 6-oxotricyclo[5.3.0.0(3,9)]decane-4-methyl carboxylate, achieved through base catalyzed rearrangement, is described. |
URI: | http://ir.niist.res.in:8080/jspui/handle/123456789/1383 |
ISSN: | 0040-4039 |
Appears in Collections: | 2006 |
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