Please use this identifier to cite or link to this item: http://localhost:8080/xmlui/handle/123456789/1383
Title: Formation of novel polycyclic cage compounds through 'uncaging' of readily accessible higher cage compounds
Authors: Beena James
Rath, N P
Suresh, E
Mangalam S Nair
Keywords: Cyclization
Polycyclic cage compounds
Issue Date: 2006
Publisher: Elsevier
Citation: Tetrahedron Letters 47(32):5775-5779;7 Aug 2006
Abstract: The synthesis of the novel cage compounds 7-halomethyl-8-(carbomethoxy)tetracyclo[4.2.1.1(4,7).0(2,5)]deca-3-(11)-ene-10-ones, methyl-4-methylene-6-oxopentacyclo[5.4.0.0.(2,5).0(3,10).0(7,9)]undecane-9-carboxylate, 3-chloromethyl-4-(carbomethoxy)tetracyclo[4.2.1.1.(3,8).0(2,5)]deca-7(11)ene-10-one, 2-bromo-5-methyl-8-methylene-6-oxotricyclo[5.3.0.0(3,9)]decane-4-carboxylic acid and 2-bromo-5-methyl-8-methylene- 6-oxotricyclo[5.3.0.0(3,9)]decane-4-methyl carboxylate, achieved through base catalyzed rearrangement, is described.
URI: http://ir.niist.res.in:8080/jspui/handle/123456789/1383
ISSN: 0040-4039
Appears in Collections:2006

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