Please use this identifier to cite or link to this item: http://hdl.handle.net/123456789/1505
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dc.contributor.authorSarath Chand, S-
dc.contributor.authorSaranya, S-
dc.contributor.authorPreethanuj, P-
dc.contributor.authorDhanya, B P-
dc.contributor.authorJijy, E-
dc.contributor.authorPraveen, P-
dc.contributor.authorSasidhar, B S-
dc.contributor.authorSzymoniak, J-
dc.contributor.authorSanthini, P V-
dc.contributor.authorRadhakrishnan, K V-
dc.date.accessioned2014-06-10T11:26:49Z-
dc.date.available2014-06-10T11:26:49Z-
dc.date.issued2014-
dc.identifier.citationOrganic & Biomolecular Chemistry 12(19):3045-3061; 2014en_US
dc.identifier.issn1477-0520-
dc.identifier.urihttp://ir.niist.res.in:8080/jspui/handle/123456789/1505-
dc.description.abstractHerein we describe our efforts on the Lewis acid catalyzed stereoselective ring-opening of pentafulvene derived diazabicyclic olefins using various ortho-functionalized aryl iodides such as 2-iodoanilines, 2-iodophenols and 2-iodobenzene thiols to access trans-1,2 disubstituted alkylidenecyclopentenes. The scope of the reaction was also explored with a range of easily available aromatic and aliphatic alcohols. Furthermore, the palladium catalyzed intramolecular Heck cyclization of trans-1,2 disubstituted alkylidenecyclopentenes would provide an easy approach for the synthesis of highly functionalized spiropentacyclic frameworks consisting of a cyclopentene fused to an indoline/benzothiophene and pyrazolidine.en_US
dc.language.isoenen_US
dc.publisherRoyal Society of Chemistryen_US
dc.subjectDiazabicyclic olefinsen_US
dc.subjectLewis aciden_US
dc.subjectOrtho-functionalized aryl iodidesen_US
dc.subjectPyrazolidineen_US
dc.subjectOrtho-functionalized aryl iodidesen_US
dc.titleTrapping the Lewis acid generated transient species from pentafulvene derived diazanorbornenes with ortho-functionalized aryl iodides and aliphatic alcoholsen_US
dc.typeArticleen_US
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