Please use this identifier to cite or link to this item:
Full metadata record
DC FieldValueLanguage
dc.contributor.authorSarath Chand, S-
dc.contributor.authorSaranya, S-
dc.contributor.authorPreethanuj, P-
dc.contributor.authorDhanya, B P-
dc.contributor.authorJijy, E-
dc.contributor.authorPraveen, P-
dc.contributor.authorSasidhar, B S-
dc.contributor.authorSzymoniak, J-
dc.contributor.authorSanthini, P V-
dc.contributor.authorRadhakrishnan, K V-
dc.identifier.citationOrganic & Biomolecular Chemistry 12(19):3045-3061; 2014en_US
dc.description.abstractHerein we describe our efforts on the Lewis acid catalyzed stereoselective ring-opening of pentafulvene derived diazabicyclic olefins using various ortho-functionalized aryl iodides such as 2-iodoanilines, 2-iodophenols and 2-iodobenzene thiols to access trans-1,2 disubstituted alkylidenecyclopentenes. The scope of the reaction was also explored with a range of easily available aromatic and aliphatic alcohols. Furthermore, the palladium catalyzed intramolecular Heck cyclization of trans-1,2 disubstituted alkylidenecyclopentenes would provide an easy approach for the synthesis of highly functionalized spiropentacyclic frameworks consisting of a cyclopentene fused to an indoline/benzothiophene and pyrazolidine.en_US
dc.publisherRoyal Society of Chemistryen_US
dc.subjectDiazabicyclic olefinsen_US
dc.subjectLewis aciden_US
dc.subjectOrtho-functionalized aryl iodidesen_US
dc.subjectOrtho-functionalized aryl iodidesen_US
dc.titleTrapping the Lewis acid generated transient species from pentafulvene derived diazanorbornenes with ortho-functionalized aryl iodides and aliphatic alcoholsen_US
Appears in Collections:2014

Files in This Item:
File Description SizeFormat 
2014-38.pdf1.06 MBAdobe PDFView/Open

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.