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Title: Bis-functionalization of 1,3-dienes through 1,4-conjugate addition of amphiphilic bis-pi-allyl and related palladium intermediates
Authors: Baiju, T V
Ajesh, V
Nayana Joseph
Preethanuj, P
Radhakrishnan, K V
Suresh, E
Yamamoto, Y
Keywords: Palladium
Allyl complexes
Michael addition
Issue Date: 2014
Publisher: Georg Thieme Verlag
Citation: Synlett 25(3):359-364;13 Feb 2014
Abstract: Palladium-catalyzed three-component coupling of allylstannane, allyl chloride and a functionalized diene is described. Regioselective 1,4-functionalization of the Michael acceptor 1,3-diene is accomplished by the amphiphilic bis--allylpalladium complex. To the best of our knowledge, this is the first time a functionalized 1,3-butadiene has been used as a Michael acceptor. The scope of the present strategy is further extended to 1,4-allylation-oxyallylation of functionalized dienes.
ISSN: 0936-5214
Appears in Collections:2014

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