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Title: Rhodium(III)-catalyzed C-H activation of phenylazoles toward C-N bond cleavage of diazabicyclic olefins: A facile access to mono- and biscyclopentenyl-functionalized aza-heteroaromatics
Authors: Praveen, P
Aparna, P S
Jijy, E
Santhini, P V
Sunil Varughese
Radhakrishnan, K V
Keywords: Rhodium
C-H activation
Bicyclic olefin
Aza heteroaromatic
Issue Date: 2014
Publisher: Georg Thieme Verlag
Citation: Synlett 25(2):275-279;23 Jan 2014
Abstract: A [RhCl2Cp*](2)-catalyzed stereoselective C-N bond cleavage of diazabicyclic olefins via C-H activation of phenylazoles in the presence of an acetate source is described. The developed method provides an easy access to biologically significant mono- and biscyclopentenyl- and alkylidenecyclopentenyl-functionalized aza heteroaromatics.
ISSN: 0936-5214
Appears in Collections:2014

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