Rhodium(III)-catalyzed C-H activation of phenylazoles toward C-N bond cleavage of diazabicyclic olefins: A facile access to mono- and biscyclopentenyl-functionalized aza-heteroaromatics

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Title:	Rhodium(III)-catalyzed C-H activation of phenylazoles toward C-N bond cleavage of diazabicyclic olefins: A facile access to mono- and biscyclopentenyl-functionalized aza-heteroaromatics
Authors:	Praveen, P Aparna, P S Jijy, E Santhini, P V Sunil Varughese Radhakrishnan, K V
Keywords:	Rhodium C-H activation Bicyclic olefin Cyclopentene Aza heteroaromatic
Issue Date:	2014
Publisher:	Georg Thieme Verlag
Citation:	Synlett 25(2):275-279;23 Jan 2014
Abstract:	A [RhCl2Cp*](2)-catalyzed stereoselective C-N bond cleavage of diazabicyclic olefins via C-H activation of phenylazoles in the presence of an acetate source is described. The developed method provides an easy access to biologically significant mono- and biscyclopentenyl- and alkylidenecyclopentenyl-functionalized aza heteroaromatics.
URI:	http://ir.niist.res.in:8080/jspui/handle/123456789/1562
ISSN:	0936-5214
Appears in Collections:	2014

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