Activation of the NC-H bond of Baylis-Hillman adducts of N-methylisatin with CAN/ROH

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Title:	Activation of the NC-H bond of Baylis-Hillman adducts of N-methylisatin with CAN/ROH
Authors:	Shanmugam, P Vaithyanathan, V Baby Viswambharan
Keywords:	Baylis Hillman adduct CH-activation Isatin Functionalized ethers Cerium(iv) ammonium-nitrate Vinyl radical cyclization Stereoselective synthesis Isomerization Hydroxylation
Issue Date:	2006
Publisher:	Elsevier
Citation:	Tetrahedron Letters 47(38):6851-6855;18 Sep 2006
Abstract:	A facile method for activation of the NC-H bond of N-methylisatin and Baylis-Hillman adducts of N-methylisatin with cerium ammonium nitrate (CAN) and saturated and unsaturated alcohols is reported. Adducts bearing an ester group at the activated alkene afford functionalized ethers, while those with a nitrile afforded ethers and nitrated aromatic products in good yield.
URI:	http://ir.niist.res.in:8080/jspui/handle/123456789/1612
ISSN:	0040-4039
Appears in Collections:	2006

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