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Title: | Dual-mode semisquaraine-based sensor for selective detection of Hg2+ in a micellar medium |
Authors: | Rekha, R A Jyothish, K Ramaiah, D |
Keywords: | Atomic absorption spectrometry Squaraine dyes Photodynamic therapy Fluorescent sensors Mercuric ion Chemodosimeter Cytotoxicity |
Issue Date: | 2007 |
Publisher: | American Chemical Society |
Citation: | Organic Letters 9(1):121-124;4 Jan 2007 |
Abstract: | A novel chemosensor based on semisquaraine dye (SSQ) for selective detection of Hg2+ is described. SSQ is obtained in quantitative yields from the reaction between squaric acid and 6-ethoxy-2-quinaldinium iodide. SSQ in combination with surfactant shows a dual chromogenic and fluorogenic response selectively toward Hg2+ as compared to Li+, Na+, K+, Ag+, Ca2+, Mg2+, Zn2+, Pb2+, Cd2+, Cu2+, and Fe3+ due to the soft acid nature and size of the mercuric ion. |
URI: | http://ir.niist.res.in:8080/jspui/handle/123456789/1614 |
ISSN: | 1523-7060 |
Appears in Collections: | 2007 |
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File | Description | Size | Format | |
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2007_00030.pdf Restricted Access | 125.07 kB | Adobe PDF | View/Open Request a copy |
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