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Title: Palladium-catalyzed interceptive decarboxylative addition of allyl carbonates with carbonyl group
Authors: Baiju, T V
Nayana Joseph
Jainu Ajit
Praveen, P
Radhakrishnan, K V
Sunil Varughese
Yamamoto, Y
Keywords: Palladium
Conjugate addition
Allyl complexes
Spiro compounds
Issue Date: 2014
Publisher: Georg Thieme Verlag
Citation: Synlett 25(9):1246-1252;Jun 2014
Abstract: The first palladium-catalyzed interceptive decarboxylative 1,4-addition of allyl carbonates with squarates is reported. Interestingly, the C-3 carbonyl group of N-substituted isatins undergoes smooth decarboxylative 1,2-addition with allyl carbonates. This transformation offers a straightforward method for the synthesis of spiro-oxepane-fused 2-oxindole.
ISSN: 0936-5214
Appears in Collections:2014

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