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Title: | Evolution of nano- to microsized spherical assemblies of a short oligo(p-phenyleneethynylene) into superstructured organogels |
Authors: | Ajayaghosh, A Reji Varghese Praveen, V K Mahesh, S |
Keywords: | Gels Nanostructures Supramolecular chemistry Pi-conjugated systems Nanocapsules |
Issue Date: | 2006 |
Publisher: | Wiley |
Citation: | Angewandte Chemie International Edition 45(20):3261-3264;12 May 2006 |
Abstract: | A subtle balance of H-bonding, π-stacking, and van der waals interactions facilitates the concentration-controlled self-assembly of a short molecular wire (see figure) into nanoparticles and fluorescent microspheres in nonpolar hydrocarbon solvents. Above a critical concentration, a blue-light emitting organogel is formed. |
URI: | http://ir.niist.res.in:8080/jspui/handle/123456789/1640 |
ISSN: | 1433-7851 |
Appears in Collections: | 2006 |
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