Chemodosimetric cyanide sensing in a 5,15-porphodimethene Pd(II) complex

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Title:	Chemodosimetric cyanide sensing in a 5,15-porphodimethene Pd(II) complex
Authors:	Holaday, M G D Tarafdar, G Adinarayana, B Reddy, M L P Srinivasan, A
Keywords:	Chemodosimetric sensor Cyanide ions Pd(II) complex 5,15-porphodimethene
Issue Date:	2014
Publisher:	Royal Society of Chemistry
Citation:	Chemical Communications 50(74):10834-10836;2014
Abstract:	The Pd(II) complex of 5,15-porphodimethene is shown as a chemodosimetric sensor where it selectively senses cyanide ions, monitored through electronic spectral analysis and identified by the naked eye. The possible binding mechanism is also proposed based on the H-1 NMR analyses. Two polymorphs of the mentioned complex are obtained by using different polar solvents and further confirmed by single crystal X-ray analyses.
URI:	http://ir.niist.res.in:8080/jspui/handle/123456789/1672
ISSN:	1359-7345
Appears in Collections:	2014

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