A mild and efficient CAN mediated oxidation of Morita–Baylis–Hillman adducts of 5-methyl-N-alkylisatin to 5-formyl-N-alkylisatin

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Title:	A mild and efficient CAN mediated oxidation of Morita–Baylis–Hillman adducts of 5-methyl-N-alkylisatin to 5-formyl-N-alkylisatin
Authors:	Shanmugam, P Vaithiyanathan, V Selvakumar, K
Keywords:	CAN Morita–Baylis–Hillman adduct Aryl methyl oxidation Isatin Aromatic aldehydes
Issue Date:	24-Mar-2008
Publisher:	Elsevier
Citation:	Tetrahedron Letters 49(13):2119-2123;24 Mar 2008
Abstract:	A simple, mild and efficient CAN mediated oxidation of Morita–Baylis–Hillman adducts of 5-methyl-N-alkylisatins 1a–13a to 5-formyl-N-alkylisatins 1b–13b under ambient reaction conditions is reported. Simple and isomerized 5-methyl-N-alkylisatin derivatives 1–4 have also been tested and failed to provide the corresponding formylated products. A plausible reaction mechanism has been proposed.
Description:	Restricted Access
URI:	http://hdl.handle.net/123456789/174
ISSN:	0040-4039
Appears in Collections:	2008

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