Synthesis of a novel cyclic donor-acceptor conjugate for selective recognition of ATP

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Title:	Synthesis of a novel cyclic donor-acceptor conjugate for selective recognition of ATP
Authors:	Prakash, P N Mahesh Hariharan Ramaiah, D
Keywords:	Molecular recognition Binding Receptors Nucleotides
Issue Date:	2005
Publisher:	American Chemical Society
Citation:	Organic Letters 7(26):5765-5768; Dec 2005
Abstract:	Novel cyclophane 1 was synthesized, and its interactions with phosphate, adenosine, AMP, ADP, and ATP have been investigated. With addition of ATP, significant decrease in absorbance of 1 was observed, whereas other guest molecules showed negligible effect. The complex between 1 and ATP was confirmed through cyclic voltammetry and H-1 NMR. The uniqueness of the system is that it complexes selectively with ATP in a cavity and involves synergistic effects of both electrostatic and pi-pi stacking interactions.
URI:	http://ir.niist.res.in:8080/jspui/handle/123456789/1764
ISSN:	1523-7060
Appears in Collections:	2005

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