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Title: | Core-modified octaphyrins: Syntheses and anion-binding properties |
Authors: | Misra, R Anand, V G Rath, H Chandrashekar, T K |
Keywords: | Anion binding Aromaticity 34pi electrons Octaphyrin Oxidative coupling reactions |
Issue Date: | 2005 |
Publisher: | Indian Academy of Sciences |
Citation: | Journal of Chemical Sciences 117(2):99-103; Mar 2005 |
Abstract: | In this paper, a brief review of the syntheses, characterization and anion-binding properties of core-modified octaphyrins is presented. It has been shown that the core-modified octaphyrins, exhibit aromaticity both in solution and in solid state, confirming the validity of the (4n + 2) Huckel rule for larger pi-electron systems. Solid-state binding characteristics of TFA anions of two core-modified octaphyrins are also described. |
URI: | http://ir.niist.res.in:8080/jspui/handle/123456789/1942 |
ISSN: | 0253-4134 |
Appears in Collections: | 2005 |
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2005_0042.pdf Restricted Access | 107.67 kB | Adobe PDF | View/Open Request a copy |
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