Please use this identifier to cite or link to this item: http://localhost:8080/xmlui/handle/123456789/2108
Title: Palladium catalyzed ring opening of azabicyclic olefins with organoindium and gallium reagents: a facile access towards benzylated cyclopentanoids
Authors: Jubi John
Adarsh, B
Radhakrishnan, K V
Keywords: Meso bicyclic hydrazines
Carbon bond formation
Functionalized cyclopentenes
Stereoselective-synthesis
Alkylidene cyclopentenes
Enantioselective desymmetrization
Allylation
Indium
Issue Date: 2010
Publisher: Elsevier
Citation: Tetrahedron 66(6):1383-1388;06 Feb 2010
Abstract: Palladium catalyzed desymmmetrization of diazabicyclic olefins with organoindium and gallium reagents were examined These reactions provided an easy access to trans-3,4-disubstituted cyclopentenes in good to excellent yields Indium reagents exhibited better reactivity compared to gallium reagents The developed methodology demonstrates a simple. clean and efficient route towards substituted cyclopentenes The present strategy provides access to benzylated cyclopentene derivatives in one pot, which forms the skeleton of a number of biologically important molecules
URI: http://ir.niist.res.in:8080/jspui/handle/123456789/2108
ISSN: 0040-4020
Appears in Collections:2010

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