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Title: | Facile synthesis of alkylidene cyclopentenes via palladium catalyzed ring opening of fulvene derived bicyclic hydrazines |
Authors: | Anas, S Sajisha, V S Jubi John Nayana Joseph, J Sholly, C G Radhakrishnan, K V |
Keywords: | Pentafulvenes Alkylidene cyclopentenes Fulvene Palladium Bicyclic hydrazines Enantioselective total-synthesis Fischer carbene complexes Linearly fused tricyclopentanoids Cycloaddition Functionalized cyclopentenes Stereoselective-synthesis Organoindium reagents Efficient synthesis Asymmetric-synthesis 3-oxidopyrylium betaine |
Issue Date: | 2008 |
Publisher: | Elsevier |
Citation: | Tetrahedron 64(41):9689-9697;06 Oct 2008 |
Abstract: | A facile synthesis of substituted alkylidene cyclopentenes through a palladium catalyzed ring opening of fulvene derived bicyclic hydrazines with various organometallic reagents is described. The products are versatile synthons with multiple points for functionalization and can be used in the synthesis of a number of biologically active molecules. |
URI: | http://ir.niist.res.in:8080/jspui/handle/123456789/2121 |
ISSN: | 0040-4020 |
Appears in Collections: | 2008 |
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2008_0156.pdf Restricted Access | 698.31 kB | Adobe PDF | View/Open Request a copy |
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