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Please use this identifier to cite or link to this item: http://localhost:8080/xmlui/handle/123456789/2198
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dc.contributor.authorVijay Nair, G-
dc.contributor.authorSreekumar, V-
dc.contributor.authorManojkumar, P-
dc.contributor.authorSuresh, E-
dc.date.accessioned2016-01-18T08:20:28Z-
dc.date.available2016-01-18T08:20:28Z-
dc.date.issued2006-
dc.identifier.citationJournal of the American Chemical Society 128(27):8736-8737;12 Jul 2006en_US
dc.identifier.issn0002-7863-
dc.identifier.urihttp://ir.niist.res.in:8080/jspui/handle/123456789/2198-
dc.description.abstractNucleophilic heterocyclic carbene-catalyzed cyclopentannulation of enals and chalcones via homoenolate has been observed for the first time. Serendipitously, the reaction lead to a very efficient synthesis of 3,4-trans-disubstituted-1-aryl cyclopentenes instead of the expected cyclopentanones. The strategy works well with thienylidene tetralone also, leading to the tricyclic cyclopentene derivative.en_US
dc.language.isoenen_US
dc.publisherAmerican Chemical Societyen_US
dc.subjectBicyclic beta-lactonesen_US
dc.subjectAsymmetric-synthesisen_US
dc.subjectConjugate additionen_US
dc.subjectGamma butyrolactonesen_US
dc.subjectAlpha,beta-unsaturated aldehydesen_US
dc.subjectMulticomponent reactionsen_US
dc.subjectNucleophilic carbenesen_US
dc.subjectAldol lactonizationen_US
dc.subjectDirect annulationsen_US
dc.subjectAcetylenic estersen_US
dc.titleN-heterocyclic carbene-catalyzed reaction of chalcones and enals via homoenolate: an efficient synthesis of 1,3,4-trisubstituted cyclopentenesen_US
dc.typeArticleen_US
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