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dc.contributor.authorPaul, A K-
dc.contributor.authorSuneesh, C K-
dc.contributor.authorJoseph, J-
dc.contributor.authorRamaiah, D-
dc.date.accessioned2016-06-08T06:54:24Z-
dc.date.available2016-06-08T06:54:24Z-
dc.date.issued2015-11-
dc.identifier.citationPhotochemistry and Photobiology 91(6):1348-1355; Nov-Dec 2015en_US
dc.identifier.urihttp://hdl.handle.net/123456789/2319-
dc.description.abstractSynthesis, photophysical and metal ion recognition properties of a series of amino acid-linked free-base and Zn-porphyrin derivatives (5–9) are reported. These porphyrin derivatives showed favorable photophysical properties including high molar extinction coefficients (>1 × 105 m-1 cm-1) for the Soret band), quantum yields of triplet excited states (63–94%) and singlet oxygen generation efficiencies (59–91%). Particularly, the Zn-porphyrin derivatives, 6 and 9 showed higher molar extinction coefficients, decreased fluorescence quantum yields, and higher triplet and singlet oxygen quantum yields compared to the corresponding free-base porphyrin derivatives. Further, the study of their interactions with various metal ions indicated that the proline-conjugated Zn-porphyrins (6 and 9) showed high selectivity toward Cu2+ ions and signaled the recogni ion through changes in fluorescence intensity. Our results provide insights on the role of nature of amino acid and metallation in the design of the porphyrin systems for application as probes and sensitizers.en_US
dc.language.isoenen_US
dc.publisherElsevieren_US
dc.titleAmino Acid-Porphyrin Conjugates: Synthesis and Study of their Photophysical and Metal Ion Recognition Propertiesen_US
dc.typeArticleen_US
Appears in Collections:2015

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