Please use this identifier to cite or link to this item: http://localhost:8080/xmlui/handle/123456789/2353
Title: Pd-catalyzed C-N coupling of vinylbromides and sulfonimidamides: A facile synthesis of N-vinylsulfonimidamides
Authors: Nandi, G C
Kota, S R
Wakchaure, P B
Chinthakindi, P K
Govender, T
Kruger, H G
Naicker, T
Arvidsson, P I
Issue Date: 2015
Publisher: Royal Society of Chemistry
Citation: RSC Advances 5(76):62084-62090; 2015
Abstract: N0-Vinyl sulfonimidamides have been synthesized through a Pd-catalyzed C–N cross coupling between the N0-(imine nitrogen) of N0-deprotected sulfonimidamides and vinyl bromides. The hitherto unreported products were obtained in moderate to excellent yield, and the C–C double bond geometry of the vinylic substrates were retained during the course of reaction. Single crystal X-ray crystallographic analysis confirmed the product structure. Furthermore, we demonstrate that the formed N0-vinyl sulfonimidamides could undergo hydrogenation with Pd–C/H2 to provide N0-alkyl sulfonimidamides
URI: http://hdl.handle.net/123456789/2353
Appears in Collections:2015

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