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Title: | meso-Tetrakis(3,5-dihydroxyphenyl)N-confused porphyrin: Influence of polar protic and aprotic solvents in tautomeric existence, exchange and morphology |
Authors: | Thomas, Ajesh P Gowri Sreedevi, K C Adinarayana, B Ramakrishnan, S Srinivasan, A |
Keywords: | Porphyrin |
Issue Date: | Jul-2013 |
Publisher: | The Royal Society of Chemistry |
Citation: | RSC Advances, 2013, 3, 16967-16972 |
Abstract: | A hitherto unknown meso-tetrakis(3,5-dihydroxyphenyl)N-confused porphyrin (NCPH) was synthesized and characterized. The typical 3H and 2H tautomeric existence of the N-confused derivative was controlled exclusively by protic and aprotic solvents rather than the established polar and non-polar driving forces. An unprecedented morphological change controlled by two tautomeric forms of NCPH during aggregation was investigated. |
URI: | http://hdl.handle.net/123456789/2483 |
Appears in Collections: | 2013 |
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