[32]p Fused Core-Modified Heptaphyrin with Mçbius Aromaticity

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DC Field	Value	Language
dc.contributor.author	Arindam Ghosh	-
dc.contributor.author	Arvind, Chaudhary	-
dc.contributor.author	Srinivasan, A	-
dc.contributor.author	Suresh, Cherumuttathu H	-
dc.date.accessioned	2016-11-16T06:00:58Z	-
dc.date.available	2016-11-16T06:00:58Z	-
dc.date.issued	2016-03	-
dc.identifier.citation	Chemistry A European journal 22,3942 –3946	en_US
dc.identifier.uri	http://hdl.handle.net/123456789/2505	-
dc.description.abstract	Anew fused core-modified 32p heptaphyrin with Mçbiusaromatic character is reported. The 1 HNMR data indicated aweak Mçbius aromaticityat298 K; however,at213–183K,the molecule predominates [4n]p Mçbiusconformation with strong diatropic ring current, which was further confirmed by X-ray analysis. The protonation experiment led to preservation of the Mçbius aromaticity at 298 K. Nevertheless, the experimental results were furthersupportedbytheoretical studies.Overall,this study represents the first example of Mçbius aromatic fused core-modified expanded porphyrin	en_US
dc.language.iso	en	en_US
dc.publisher	wiley	en_US
dc.subject	Mçbius aromaticity	en_US
dc.subject	molecule	en_US
dc.subject	diatropic	en_US
dc.subject	theoretical	en_US
dc.subject	aromatic	en_US
dc.title	[32]p Fused Core-Modified Heptaphyrin with Mçbius Aromaticity	en_US
dc.type	Article	en_US
Appears in Collections:	2016

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