Desymmetrization of meso-Bicyclic Hydrazines: An Efficient Strategy Towards the Synthesis of Functionalized Cyclopentenes

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Title:	Desymmetrization of meso-Bicyclic Hydrazines: An Efficient Strategy Towards the Synthesis of Functionalized Cyclopentenes
Authors:	Sajisha, V S Anas, S Jubi John Radhakrishnan, K V
Keywords:	meso-bicyclic hydrazines cyclopentenes palladium homogenous catalysis
Issue Date:	2009
Publisher:	Thieme
Citation:	Synlett, (18):2885-2895
Abstract:	Desymmetrization of meso-bicyclic hydrazines offers a facile entry into the class of functionalized cyclopentenes. Various methodologies used along this direction are described in this account. Our attempts in this area proved that the palladium-catalyzed desymmetrization of these substrates with various organometallic reagents results in the formation of 3,4-disubstituted cyclopentenes.
URI:	http://hdl.handle.net/123456789/2557
Appears in Collections:	2009

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