Ion Imprinted Polymer based Ion-selective Electrode for the Trace Determination of Dysprosium(III) Ions

Abstract

Ion-selective electrode (ISE) was designed by dispersing the dysprosium(III) IIP particles in 2-nitrophenyloctyl ether plasticizer and then embedded in polyvinyl chloride matrix. The ISE shows a Nernstian response for dysprosium(III) over a wide concentration range (8.0 × 10−6 to 1.0 × 10−1 M) with a slope of 21.7 mV per decade. The limit of detection was 2 × 10−6 M. This sensor has a very fast response time (∼10 s) and offers high selectivity compared to conventional chemical sensors towards dysprosium(III) with respect to several alkali, alkaline earth and transition metal ions as the selectivity is 10–100-fold better. The sensor was used for determination of dysprosium(III) ions by potentiometric (EDTA) titration and has been successfully demonstrated for the determination of fluoride in mouth wash solution.