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Title: | Lewis Acid Catalyzed Regioselective Hydroheteroarylation of Pentafulvenes |
Authors: | Sarath Chand, S Greeshma, Gopalan Santhini, P V Preethanuj, P Jubi, John Dominique, Harakat Florian, Jaroschik Radhakrishnan, K V |
Keywords: | exocyclic carbon acetonitrile cyclopentadienyl endocyclic ring |
Issue Date: | 10-Feb-2016 |
Publisher: | ACS publication |
Citation: | Organic letters 18:964−967 |
Abstract: | A diverse approach toward the catalytic regioselective nucleophilic addition of nitrogen heterocycles to Lewis acid activated pentafulvenes has been established. The developed protocol introduces pentafulvenes as nonsymmetrical alkenes for the hydroheteroarylation reaction, providing alkylidenecyclopentenylation at the C-3 position of indoles and the C-2 position of pyrrole |
URI: | http://hdl.handle.net/123456789/2812 |
Appears in Collections: | 2016 |
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lewics acid-organic letters-sarath chand.pdf Restricted Access | 629.32 kB | Adobe PDF | View/Open Request a copy |
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