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Title: Accessing Highly Functionalized Cyclopentanoids: Via a Cascade Palladation Approach: Unprecedented Benzylic C-H Activation Towards Cyclopentenoindanes
Authors: Santhini, P V
Smrithy, A S
Irfana Jesin, C P
Sunil Varughese
Jubi John
Radhakrishnan, K V
Issue Date: 23-Feb-2018
Publisher: The Royal Society of Chemistry
Citation: Chemical Communications, 54(24):2982-2985 
Abstract: A Pd-catalyzed synthesis of 3,4,5-trisubstituted cyclopentenes from diazabicyclic olefins and o-iodobenzoates has been developed. The hitherto unknown cascade process involves three stages: carbopalladation, oxypalladation and a Tsuji–Trost reaction. We have also developed a facile route involving a novel benzylic C–H activation towards cyclopentenoindane moieties.
Appears in Collections:2018

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