Accessing Highly Functionalized Cyclopentanoids: Via a Cascade Palladation Approach: Unprecedented Benzylic C-H Activation Towards Cyclopentenoindanes

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Title:	Accessing Highly Functionalized Cyclopentanoids: Via a Cascade Palladation Approach: Unprecedented Benzylic C-H Activation Towards Cyclopentenoindanes
Authors:	Santhini, P V Smrithy, A S Irfana Jesin, C P Sunil Varughese Jubi John Radhakrishnan, K V
Issue Date:	23-Feb-2018
Publisher:	The Royal Society of Chemistry
Citation:	Chemical Communications, 54(24):2982-2985
Abstract:	A Pd-catalyzed synthesis of 3,4,5-trisubstituted cyclopentenes from diazabicyclic olefins and o-iodobenzoates has been developed. The hitherto unknown cascade process involves three stages: carbopalladation, oxypalladation and a Tsuji–Trost reaction. We have also developed a facile route involving a novel benzylic C–H activation towards cyclopentenoindane moieties.
URI:	http://10.10.100.66:8080/xmlui/handle/123456789/3075
Appears in Collections:	2018

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