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dc.contributor.authorThomas, T G-
dc.contributor.authorChandra Shekar, S-
dc.contributor.authorSwathi, R S-
dc.contributor.authorGopidas, K R-
dc.date.accessioned2018-06-19T11:29:13Z-
dc.date.available2018-06-19T11:29:13Z-
dc.date.issued2017-01-03-
dc.identifier.citationRSC Advances, 7(2):821-825en_US
dc.identifier.urihttp://10.10.100.66:8080/xmlui/handle/123456789/3113-
dc.description.abstractThe highly symmetric and stable triazatruxene radical cation was generated chemically for the first time. The intervalence charge transfer (IV-CT) absorption band of the radical cation was observed at 7500–12 500 cm 1. The IV-CT band exhibited a well-resolved, solvent independent vibrational structure which prompted us to classify the radical cation as a Robin and Day class III IV-CT compound. The assignment was examined in light of two previously reported semiclassical models for three-center IV-CT systems. The triazatruxene radical cation is the first and only example of a three-center class III IVCT system.en_US
dc.language.isoenen_US
dc.publisherRoyal Society of Chemistryen_US
dc.titleTriazatruxene Radical Cation: A Trigonal Class III Mixed Valence Systemen_US
dc.typeArticleen_US
Appears in Collections:2017

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