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DC Field | Value | Language |
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dc.contributor.author | Thomas, T G | - |
dc.contributor.author | Chandra Shekar, S | - |
dc.contributor.author | Swathi, R S | - |
dc.contributor.author | Gopidas, K R | - |
dc.date.accessioned | 2018-06-19T11:29:13Z | - |
dc.date.available | 2018-06-19T11:29:13Z | - |
dc.date.issued | 2017-01-03 | - |
dc.identifier.citation | RSC Advances, 7(2):821-825 | en_US |
dc.identifier.uri | http://10.10.100.66:8080/xmlui/handle/123456789/3113 | - |
dc.description.abstract | The highly symmetric and stable triazatruxene radical cation was generated chemically for the first time. The intervalence charge transfer (IV-CT) absorption band of the radical cation was observed at 7500–12 500 cm 1. The IV-CT band exhibited a well-resolved, solvent independent vibrational structure which prompted us to classify the radical cation as a Robin and Day class III IV-CT compound. The assignment was examined in light of two previously reported semiclassical models for three-center IV-CT systems. The triazatruxene radical cation is the first and only example of a three-center class III IVCT system. | en_US |
dc.language.iso | en | en_US |
dc.publisher | Royal Society of Chemistry | en_US |
dc.title | Triazatruxene Radical Cation: A Trigonal Class III Mixed Valence System | en_US |
dc.type | Article | en_US |
Appears in Collections: | 2017 |
Files in This Item:
File | Description | Size | Format | |
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Triazatruxene radical cation - Thomas T G - RSC Advances.pdf Restricted Access | 433.5 kB | Adobe PDF | View/Open Request a copy |
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