Pd-Catalyzed Oxidative Annulation of Enamides with Diazabicyclic Olefins: Rapid Access to Cyclopentene Fused 2-Pyrrolines

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Title:	Pd-Catalyzed Oxidative Annulation of Enamides with Diazabicyclic Olefins: Rapid Access to Cyclopentene Fused 2-Pyrrolines
Authors:	Santhini, P V Nimisha, G Jubi John Suresh, E Luxmi Varma, R Radhakrishnan, K V
Issue Date:	7-Feb-2017
Publisher:	Royal Society of Chemistry
Citation:	Chemical Communications, 53(11):1848-1851
Abstract:	An efficient stereoselective route for the synthesis of cyclopentene fused 2-pyrrolines has been established via a Pd-catalyzed C–H activation/oxidative coupling of aryl enamides with diazabicyclic olefins. The proposed two-stage mechanismwas successfully proven by isolating the intermediate trans-disubstituted cyclopentene.
URI:	http://10.10.100.66:8080/xmlui/handle/123456789/3199
Appears in Collections:	2017

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