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Title: Pd-Catalyzed Oxidative Annulation of Enamides with Diazabicyclic Olefins: Rapid Access to Cyclopentene Fused 2-Pyrrolines
Authors: Santhini, P V
Nimisha, G
Jubi John
Suresh, E
Luxmi Varma, R
Radhakrishnan, K V
Issue Date: 7-Feb-2017
Publisher: Royal Society of Chemistry
Citation: Chemical Communications, 53(11):1848-1851 
Abstract: An efficient stereoselective route for the synthesis of cyclopentene fused 2-pyrrolines has been established via a Pd-catalyzed C–H activation/oxidative coupling of aryl enamides with diazabicyclic olefins. The proposed two-stage mechanismwas successfully proven by isolating the intermediate trans-disubstituted cyclopentene.
Appears in Collections:2017

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