Tandem alpha-Arylation/Cyclization of 4-Haloacetoacetates with Arynes: A Metal-Free Approach toward 4-Aryl-3-(2H)-furanones

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DC Field	Value	Language
dc.contributor.author	J, John	-
dc.contributor.author	V K, Omanakuttan	-
dc.contributor.author	T, Aneeja	-
dc.contributor.author	C H, Suresh	-
dc.contributor.author	P G, Jones	-
dc.contributor.author	H, Hopf	-
dc.date.accessioned	2020-02-25T14:44:32Z	-
dc.date.available	2020-02-25T14:44:32Z	-
dc.date.issued	2019-04-04	-
dc.identifier.citation	The Journal of Organic Chemistry; 84(9):5957-5964	en_US
dc.identifier.uri	https://pubs.acs.org/doi/pdf/10.1021/acs.joc.9b00488	-
dc.identifier.uri	http://10.10.100.66:8080/xmlui/handle/123456789/3571	-
dc.description.abstract	An efficacious, metal-free strategy has been developed for the synthesis of 4-aryl-3-(2H)-furanones. The reaction proceeds via the nucleophilic addition of an active methylene compound to the aryne followed by ring closing of the adduct. The reaction proceeds under mild conditions, is applicable for gram-scale synthesis of 4-aryl-3-(2H)-furanones, and is general for a range of substituted arynes and ring closing	en_US
dc.language.iso	en	en_US
dc.publisher	American Chemical Society	en_US
dc.subject	Furanones	en_US
dc.subject	Ring closing	en_US
dc.title	Tandem alpha-Arylation/Cyclization of 4-Haloacetoacetates with Arynes: A Metal-Free Approach toward 4-Aryl-3-(2H)-furanones	en_US
dc.type	Article	en_US
Appears in Collections:	2019

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