Alpha,beta-(C-C-C) agostic bonds in transition metal based olefin metathesis catalyses

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Title:	Alpha,beta-(C-C-C) agostic bonds in transition metal based olefin metathesis catalyses
Authors:	Suresh, C H Baik, M-H
Keywords:	Alpha,beta-(C - C - C) agostic bond Olefin metathesis catalysis 14-electron metallacyclobutane 16-electron alkylidene analogue
Issue Date:	2005
Publisher:	The Royal Society of Chemistry
Citation:	Dalton Transactions (18): 2982-2984; 2005
Abstract:	An alpha,beta-(C - C - C) agostic bond is found to provide the additional stabilization needed to make the formally 14-electron metallacyclobutane intermediate lower in energy than its 16-electron alkylidene analogue during olefin metathesis catalysis.
URI:	http://hdl.handle.net/123456789/3659
ISSN:	1477-9226
Appears in Collections:	2005

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