Isosmaragdyrin with an N3C2 core: stabilization of Rh(i) and organo-Pt(ii) complexes†Isosmaragdyrin with an N3C2 core: stabilization of Rh(i) and organo-Pt(ii) complexes

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Title:	Isosmaragdyrin with an N3C2 core: stabilization of Rh(i) and organo-Pt(ii) complexes†Isosmaragdyrin with an N3C2 core: stabilization of Rh(i) and organo-Pt(ii) complexes
Authors:	Das, M Chitranshi, S Murugavel, M Adinarayana, B Suresh, CH Srinivasan, A
Keywords:	isosmaragdyrin organometallic complex porphyrin
Issue Date:	2020
Publisher:	Royal Society of Chemistry
Citation:	Chemical Communications;56(24):3551-3554
Abstract:	Isosmaragdyrin with an N3C2 core is successfully achieved by introducing a 2,6-di-m-phenylpyridine unit. The core is utilized to stabilize the Rh(I) ion in the N–Rh(I)–N bonding mode and the Pt(II) ion in the (N^C)N fashion to form an unsymmetrical pincer-type organometallic complex.
URI:	https://doi.org/10.1039/d0cc00214c http://hdl.handle.net/123456789/3828
Appears in Collections:	2020

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