Please use this identifier to cite or link to this item: http://localhost:8080/xmlui/handle/123456789/4095
Title: Pd/Fe3O4 Supported on Bio-waste Derived Cellulosic-carbon as a Nanocatalyst for C-C Coupling and Electrocatalytic Application
Authors: Kandathil, V
Moolakkil, A
Kulkarni, P
Veetil, A K
Somappa, SB
Keywords: biowaste
cellulosic-carbon
Pd/Fe3O4
Hiyama cross-coupling
hydrogen evolution reaction
recyclabili
Issue Date: 10-Jul-2022
Publisher: Springer
Citation: Frontiers of Chemical Science and Engineering
Abstract: The current work describes the synthesis of a new bio-waste derived cellulosic-carbon supportedpalladium nanoparticles enriched magnetic nanocatalyst (Pd/Fe3O4@C) using a simple multi-step process under aerobic conditions. Under mild reaction conditions, the Pd/Fe3O4@C magnetic nanocatalyst demonstrated excellent catalytic activity in the Hiyama cross-coupling reaction for a variety of substrates. Also, the Pd/Fe3O4@C magnetic nanocatalyst exhibited excellent catalytic activity up to five recycles without significant catalytic activity loss in the Hiyama cross-coupling reaction. Also, we explored the use of Pd/Fe3O4@C magnetic nanocatalyst as an electrocatalyst for hydrogen evolution reaction. Interestingly, the Pd/Fe3O4@C magnetic nanocatalyst exhibited better electrochemical activity compared to bare carbon and magnetite (Fe3O4 nanoparticles) with an overpotential of 293 mV at a current density of 10 mA·cm–2
URI: https://doi.org/10.1007/s11705-022-2158-y
http://localhost:8080/xmlui/handle/123456789/4095
Appears in Collections:2022



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