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dc.contributor.authorOmanakuttan, V K-
dc.contributor.authorAlisha, V-
dc.contributor.authorHenning, H-
dc.contributor.authorJubi, J-
dc.date.accessioned2023-05-08T09:41:52Z-
dc.date.available2023-05-08T09:41:52Z-
dc.date.issued2023-02-13-
dc.identifier.citationOrganics; 4(1):70-85en_US
dc.identifier.urihttps://www.mdpi.com/2673-401X/4/1/6-
dc.identifier.urihttp://localhost:8080/xmlui/handle/123456789/4475-
dc.description.abstractWe have realized a Pd-catalyzed ring-opening of diazabicyclic olefins with 4-halo-1,3-dicarbonyl compounds. This reaction resulted in the formation of 3(2H)-furanone-appended hydrazino cyclopentenes. The reaction proceeds via the formation of a π-allylpalladium intermediate which is attacked by the active methylene species, and an intramolecular nucleophilic substitution in the 4-halo-1,3-dicarbonyl moiety furnishes the 3(2H)-furanone-substituted cyclopentene. We could extend this methodology to cyclopropane-appended spirotricyclic olefin for synthesizing 3(2H)-furanone-substituted spiro[2.4]hept-5-ene.en_US
dc.language.isoenen_US
dc.publisherMDPIen_US
dc.subject3(2H)-furanoneen_US
dc.subjectdiazabicyclic olefinsen_US
dc.subject4-halo-1,3-dicarbonyl compoundsen_US
dc.titlePalladium Catalyzed Ring-Opening of Diazabicylic Olefins with 4-Halo-1,3-Dicarbonyl Compounds: Accessing 3(2H)-Furanone-Appended Cyclopentenesen_US
dc.typeArticleen_US
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