Synthesis and properties of amphiphilic photoresponsive gelators for aromatic solvents

Abstract

A sugar-based photoresponsive supergelator, N-glycosylazobenzene that shows selective gelation of aromatic solvents is described. The partialtrans cis isomerization of the azobenzene moiety allows photoinduced chopping of the entangled gel fibers to short fibers, resulting in controlled fiber length and gel sol transition. The gelator is useful for the selective removal of toxic aromatic solvents from water.