A 6,11,16-Triarylbiphenylcorrole with an adj-CCNN Core: Stabilization of an Organocopper(III) Complex

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Title:	A 6,11,16-Triarylbiphenylcorrole with an adj-CCNN Core: Stabilization of an Organocopper(III) Complex
Authors:	Adinarayana, B Thomas, A P Suresh, C H Srinivasan, A
Keywords:	A 6,11,16-Triarylbiphenylcorrole anadj-CCNN Core
Issue Date:	1-Sep-2015
Publisher:	Wiley
Citation:	Angewandte Chemie;127(36):10624-10628
Abstract:	An adj-dicarbacorrole with CCNN in the core is achieved by replacing the bipyrrole moiety by a simple polycyclic aromatic hydrocarbon, such as biphenyl unit. Spectroscopic studies and structural analyzes confirm the absence of macrocyclic aromatization, thus leading to overall nonaromatic character. The trianionic core is effectively utilized to stabilize a copper(III) ion to form an organocopper complex.
URI:	https://doi.org/10.1002/ange.201503347 http://localhost:8080/xmlui/handle/123456789/4776
Appears in Collections:	2015

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