Proximity-induced FRET and charge-transfer between quantum dots and curcumin enable reversible thermochromic hybrid polymeric films

Abstract

This study introduces a novel strategy for developing reversible thermochromic fluorescent films by precisely controlling the nanoscale proximity of boron nitride quantum dots and curcumin molecules within a poly(3-hydroxybutyrate) matrix. The synergistic interaction and Förster resonance energy transfer between these fluorophores result in an energy transfer efficiency of ∼94%. This approach enables tunable color changes in response to temperature variations, governed by the segmental mobility of polymer chains. Practical applications of these films as temperature sensors for water bottles and electronic devices are demonstrated, highlighting their potential in temperature monitoring, smart packaging, and thermal management systems.