Pentafulvene-derived η3-allyltitanocenes as intermediates for the stereoselective functionalization of 5-membered carbocycles.

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Title:	Pentafulvene-derived η3-allyltitanocenes as intermediates for the stereoselective functionalization of 5-membered carbocycles.
Authors:	Joseph, J Jaroschik, F Radhakrishnan, K V Vasse, Jean-Luc Szymoniak, J
Keywords:	Fischer carbene complexes 6+3 Cycloaddition Crystal-structure 7-Membered ring Aldol reactions
Issue Date:	2013
Publisher:	Royal Society of Chemistry
Citation:	Chemical Communications 49(40):4549-4551;2013
Abstract:	Allyltitanocene complexes can be generated by reacting pentafulvenes with DIBAL-H and Cp2TiCl2. Their coupling with aldehydes affords homoallylic alcohols in a highly regio- and stereoselective manner. The potential of this method for the stereoselective synthesis of cyclopentane derivatives is illustrated.
URI:	http://hdl.handle.net/123456789/579
Appears in Collections:	2013

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