Please use this identifier to cite or link to this item: http://localhost:8080/xmlui/handle/123456789/579
Title: Pentafulvene-derived η3-allyltitanocenes as intermediates for the stereoselective functionalization of 5-membered carbocycles.
Authors: Joseph, J
Jaroschik, F
Radhakrishnan, K V
Vasse, Jean-Luc
Szymoniak, J
Keywords: Fischer carbene complexes
6+3 Cycloaddition
7-Membered ring
Aldol reactions
Issue Date: 2013
Publisher: Royal Society of Chemistry
Citation: Chemical Communications 49(40):4549-4551;2013
Abstract: Allyltitanocene complexes can be generated by reacting pentafulvenes with DIBAL-H and Cp2TiCl2. Their coupling with aldehydes affords homoallylic alcohols in a highly regio- and stereoselective manner. The potential of this method for the stereoselective synthesis of cyclopentane derivatives is illustrated.
Appears in Collections:2013

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