Please use this identifier to cite or link to this item: http://hdl.handle.net/123456789/620
Title: Rhodium catalyzed oxidative coupling of salicylaldehydes with diazabicyclic olefins: a one pot strategy involving aldehyde C-H cleavage and pi-allyl chemistry towards the synthesis of fused ring chromanones
Authors: Jijy, E
Praveen, P
Shimi, M
Pihko, P M
Nayana Joseph
Radhakrishnan, K V
Keywords: Meso bicyclic hydrazines
Enantioselective desymmetrization
Intermolecular hydroacylation
Stereoselective-synthesis
Reagents
Cyclopentannulation
Transformations
Cyclopentenes
Annulation
alkenes
Issue Date: 2013
Publisher: Royal Society of Chemistry
Citation: Chemical Communications 49(66):7349-7351; 2013
Abstract: An efficient one pot strategy for the synthesis of cyclopentene fused chromanone derivatives through the direct oxidative coupling of salicylaldehydes with bicyclic olefins in the presence of a rhodium-copper catalyst system is described. This is the first report on the ring opening-ring closing of bicyclic hydrazines via metal catalyzed oxidative coupling reaction.
URI: http://hdl.handle.net/123456789/620
Appears in Collections:2013

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