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dc.contributor.authorNayana Joseph-
dc.contributor.authorRani Rajan-
dc.contributor.authorJubi John-
dc.contributor.authorDevika, N V-
dc.contributor.authorSarath Chand, S-
dc.contributor.authorSuresh, E-
dc.contributor.authorPihko, P M-
dc.contributor.authorRadhakrishnan, K V-
dc.date.accessioned2013-09-28T04:40:09Z-
dc.date.available2013-09-28T04:40:09Z-
dc.date.issued2013-
dc.identifier.citationRSC Advances 3(21):7751-7757;2013en_US
dc.identifier.urihttp://hdl.handle.net/123456789/632-
dc.description.abstractA simple and efficient method for the stereoselective ring opening of bicyclic hydrazines with various aryl halides under palladium catalysis has been elaborated. The reactions afforded trans-3,4-disubstituted cyclopentenes or alkylidene cyclopentenes in good to excellent yields. By taking advantage of multiple points of functionalization in the synthesized trans-3-phenyl-4-hydrazino-cyclopentene, we have synthesized the antidepressant Cypenamine (trans-2-phenylcyclopentylamine).en_US
dc.language.isoenen_US
dc.publisherRoyal Society of Chemistryen_US
dc.subjectMeso bicyclic hydrazinesen_US
dc.subjectFacile synthesisen_US
dc.subjectEnantioselective desymmetrizationen_US
dc.subjectFunctionalized cyclopentenesen_US
dc.subjectStereoselective-synthesisen_US
dc.subjectGlycosidase inhibitorsen_US
dc.subjectDiazabicyclic alkenesen_US
dc.subjectTertiary-aminesen_US
dc.subjectReagentsen_US
dc.subjectCyclopentannulationen_US
dc.titleAn exclusive approach to 3,4-disubstituted cyclopentenes and alkylidene cyclopentenes via the palladium catalyzed ring opening of azabicyclic olefins with aryl halidesen_US
dc.typeArticleen_US
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