Please use this identifier to cite or link to this item: http://localhost:8080/xmlui/handle/123456789/66
Title: Silica chloride – catalyzed one-post isomerization – chlorination, arylation, and etherification of Baylis-Hillman adducts
Authors: Shanmugam, P
Baby Viswambharan
Vaithiyanathan, V
Keywords: Silica chloride catalyst
Baylis-Hillman adducts
One pot isomerization
Chlorination reaction
Arylation
Etherification
Issue Date: 2007
Publisher: CSIRO Publishing
Citation: Australian Journal of Chemistry 60(11):850-856;2007
Abstract: A convenient and efficient one-pot isomerization-chlorination, arylation, and etherification of several Baylis-Hillman adducts with silica chloride, an eco-friendly heterogeneous catalyst, silica chloride-arenes, and silica chloride-saturated and unsaturated alcohols as reagent systems are reported. These reactions furnished highly functionalized isomerized Baylis-Hillman derivatives in good yield. The efficiency and necessity of silica chloride catalyst was compared with thionyl chloride. A plausible mechanism of the reaction is proposed.
URI: http://hdl.handle.net/123456789/66
Appears in Collections:2007

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