Silica chloride – catalyzed one-post isomerization – chlorination, arylation, and etherification of Baylis-Hillman adducts

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DC Field	Value	Language
dc.contributor.author	Shanmugam, P	-
dc.contributor.author	Baby Viswambharan	-
dc.contributor.author	Vaithiyanathan, V	-
dc.date.accessioned	2011-03-16T04:48:26Z	-
dc.date.available	2011-03-16T04:48:26Z	-
dc.date.issued	2007	-
dc.identifier.citation	Australian Journal of Chemistry 60(11):850-856;2007	en_US
dc.identifier.other	152-2007	-
dc.identifier.uri	http://hdl.handle.net/123456789/66	-
dc.description.abstract	A convenient and efficient one-pot isomerization-chlorination, arylation, and etherification of several Baylis-Hillman adducts with silica chloride, an eco-friendly heterogeneous catalyst, silica chloride-arenes, and silica chloride-saturated and unsaturated alcohols as reagent systems are reported. These reactions furnished highly functionalized isomerized Baylis-Hillman derivatives in good yield. The efficiency and necessity of silica chloride catalyst was compared with thionyl chloride. A plausible mechanism of the reaction is proposed.	en_US
dc.language.iso	en	en_US
dc.publisher	CSIRO Publishing	en_US
dc.subject	Silica chloride catalyst	en_US
dc.subject	Baylis-Hillman adducts	en_US
dc.subject	One pot isomerization	en_US
dc.subject	Chlorination reaction	en_US
dc.subject	Arylation	en_US
dc.subject	Etherification	en_US
dc.title	Silica chloride – catalyzed one-post isomerization – chlorination, arylation, and etherification of Baylis-Hillman adducts	en_US
dc.type	Article	en_US
niist.citation		-
Appears in Collections:	2007

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