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Title: A facile and efficient stereoselective synthesis of highly functionalized trisubstituted alkene derivatives of ferrocenealdehyde
Authors: Shanmugam, P
Vaithiyanathan, V
Baby Viswambharan
Suchithra, M
Keywords: Baylis Hillman adduct
Carbon nucleophile
Eglinton coupling reaction
Carbon-carbon bond reaction
Clay catalyzed reaction
Issue Date: 24-Dec-2007
Publisher: Elsevier
Citation: Tetrahedron Letters 48(52):9190-9194;24 Dec 2007
Abstract: The reaction of the Baylis-Hillman adduct 2 of ferrocenealdehyde with various oxygen and carbon nucleophiles in the presence of montmorillonite K10 clay catalyst furnished highly functionalised trisubstituted alkene derivatives of ferrocenealdehyde in excellent yield. Synthetic use of one of products 7 has been demonstrated with the synthesis of a 1,3-diyne ether derivative of ferrocene 11 via an Eglinton coupling reaction.
Appears in Collections:2007

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