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Title: Palladium catalyzed 1, 8-conjugate addition to heptafulvene via bis-pi-allyl palladium complexes
Authors: George, S C
Sreeja, T
Anas, S
Radhakrishnan, K V
Yamamoto, Y
Keywords: Activated olefins
Cycloaddition reactions
8, 8-Dicyano-3-(4'-N, N-Dimethylamino) Phenylheptafulvene
1, 6-Addition
Issue Date: 2011
Publisher: American Chemical Society
Citation: Organic Letters 13(19):4984-4987;07 Oct 2011
Abstract: The palladium catalyzed 1, 8-conjugate addition of heptafulvene, an antiaromatic conjugated 8 pi-electron system, is discussed. The method is utilized for the concise synthesis of bis-functionalized cycloheptatriene (CHT) derivatives. This is the first report on the palladium catalyzed bisfunctionalization of a cyclic cross conjugated system.
ISSN: 1523-7060
Appears in Collections:2011

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