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Please use this identifier to cite or link to this item: http://localhost:8080/xmlui/handle/123456789/782
Title: Nucleophilic heterocyclic carbene catalyzed annulation of enals to chalcones in methanol: A stereoselective synthesis of highly functionalized cyclopentanes
Authors: Vijay Nair, G
Beneesh, P B
Sreekumar, V
Vimal Varghese
Anabha, E R
Suresh, E
Keywords: Gamma-Butyrolactones
Homoenolate reagents
Carbonyl compounds
Stetter reaction
Organocatalysis
Esters
Deprotonation
Issue Date: 2009
Publisher: American Chemical Society
Citation: Organic Letters 11(12):2507-2510;18 Jun 2009
Abstract: Homoenolates generated from enals by nucleophilic heterocyclic carbene (NHC) catalysis undergo annulation with chalcones in methanol to afford methyl beta-hydroxycyclopentanecarboxylates, stereoselectively. Construction of four contiguous stereocenters in a stereoselective manner is noteworthy.
URI: http://ir.niist.res.in:8080/jspui/handle/123456789/782
ISSN: 1523-7060
Appears in Collections:2009

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