Cu (II) mediated generation and spectroscopic study of the Tris(4-anisyl)amine radical cation and dication. Unusually shielded chemical shifts in the dication

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Title:	Cu (II) mediated generation and spectroscopic study of the Tris(4-anisyl)amine radical cation and dication. Unusually shielded chemical shifts in the dication
Authors:	Sreenath, K Thomas, T G Gopidas, K R
Keywords:	Electron-paramagnetic-resonance Photoinduced charge separation Inverted region Aromatic-amines Triarylamines Carbocations Temperature Carbodications Route Ions
Issue Date:	2011
Publisher:	American Chemical Society
Citation:	Organic Letters 13(5):1134-1137;04 Mar 2011
Abstract:	The reaction of tris(4-anisyl)amine (TAA) with Cu(2+) ion leading to formation of the TAA radical cation and dication is described. Spectroscopic studies confirm the formation of the radical cation and dication. (1)H and (13) C NMR spectral studies reveal interesting structural features of the dication.
URI:	http://ir.niist.res.in:8080/jspui/handle/123456789/835
ISSN:	1523-7060
Appears in Collections:	2011

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