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Browsing by Author "Aravindakumar, C T"

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Dimer radical cation of 4-thiouracil: a pulse radiolysis and theoretical study

Prasanthkumar, K P; Suresh, Cherumuttathu H; Aravindakumar, C T (wiley onlinelibrary.com, 2013-04-30)

Pulse radiolysis with optical absorption detection has been used to study the reactions of hydroxyl radical (OH•) with 4-thiouracil (4TU) in aqueous medium. The transient absorption spectrum for the reaction of OH• with ...
Oxidation reactions of 2‑Thiouracil: A theoretical and pulse radiolysis study

Prasanthkumar, K P; Suresh, C H; Aravindakumar, C T (American Chemical Society, 2012-11-08)

The reaction of hydroxyl radical (•OH) with the nucleic acid base analogue 2-thiouracil (1) has been studied by pulse radiolysis experiments and DFT. The generic intermediate radicals feasible for the •OH reactions with ...
Reaction of hydroxyl radicals with azacytosines: A pulse radiolysis and theoretical study

Pramod, G; Prasanthn Kumar, K P; Hari Mohan; Manoj, V M; Manoj, P; Suresh, C H; Aravindakumar, C T (American Chemical Society, 2006)

Pulse radiolysis and density functional theory (DFT) calculations at B3LYP/6-31+G(d,p) level have been carried out to probe the reaction of the water-derived hydroxyl radicals ((OH)-O-center dot) with 5-azacytosine (5Ac) ...
Theoretical study of the addition and abstraction reactions of hydroxyl radical with uracil

Prasanthkumar, K P; Suresh, C H; Aravindakumar, C T (Elsevier, 2012-03)

The addition as well as abstraction reactions of hydroxyl radical(dOH) with the nucleic acid base,uracil(U), in the gasphasehasbeenexploredattheB3LYP/6-31þG(d,p)level of density functional theory (DFT). The energy barrier ...

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