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Browsing by Author "Thiyagarajan, S"

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Catalytic Formal Conjugate Addition: Direct Synthesis of Delta-Hydroxynitriles from Nitriles and Allylic Alcohols

Thiyagarajan, S; Sankar, R V; Anjalikrishna, P K; Suresh, C H; Gunanathan, C (ACS Publications, 2022-02-18)

Alcohols and nitrile functionalities have widespread applications in biochemical and chemical synthesis. Catalytic transformations involving C–C bond formation relying on unsaturated coupling partners create important ...
Functional characterization and substrate specificity analysis of D6-desaturase from marine microalga Isochrysis sp.

Thiyagarajan, S; Arumugam, M; Senthil, N; Vellaikumar, S; Kathiresan, S (Springer, 2018-03)

Objectives To express a D6-desaturase gene and produce gamma-linolenic acid (GLA) and stearidonic acid (SDA) in prokaryotic expression system (Escherichia coli), and analyze its substrate specificity in the omega-3 fatty ...
Heterologous Production of Polyunsaturated Fatty Acids in E. coli Using Δ5-Desaturase Gene from Microalga Isochrysis Sp.

Thiyagarajan, S; Khandelwal, P; Senthil, N; Vellaikumar, S; Arumugam, M; Dubey, A A; Kathiresan, S (Springer Nature, 2021-03)

Eicosapentaenoic acid (EPA) and arachidonic acid (ARA) are long-chain polyunsaturated fatty acids (PUFAs) that play a significant role in human growth and development, which deficiency can trigger several metabolic-related ...
Identification and Functional Characterization of Two Novel Fatty Acid Genes from Marine Microalgae for Eicosapentaenoic Acid Production

Thiyagarajan, S; Arumugam, M; Kathiresan, S (Springer, 2020-04)

Marine microalgae such as Isochrysis sp. and Pavlova sp. are the predominant source of polyunsaturated fatty acids (PUFAs) such as eicosapentaenoic acid (EPA, 20:5n–3) and docosahexaenoic acid (DHA, 22:6n–3). EPA biosynthesis ...
Ruthenium(II)-catalyzed regioselective 1,2-hydrosilylation of N‑heteroarenes and tetrel bonding mechanism

Behera, D; Thiyagarajan, S; Anjalikrishna, P K; Suresh, C H; Gunanathan, C (American Chemical Society, 2021-05-21)

An efficient regioselective dearomatization of N-heteroarenes using a ruthenium precatalyst [Ru-(p-cymene)(PCy3)Cl2] 1 is achieved. Reactions were performed under mild and neat conditions. A wide variety of N-heteroarenes ...

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