Browsing by Subject "C–H activation"

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Diazanorbornene: A Valuable Synthon towards Carbocycles and Heterocycles

Preethanuj, P; Jijy, E; Prakash, P; Sarngadharan, SC; Vijayan, A; Radhakrishnan, KV; John, J (Wiley, 2020-11-15)

Desymmetrization of meso compounds is well recognized as a powerful method for delivering biologically relevant molecular skeletons in a few synthetic steps. Heterobicyclic olefins are a class of meso compounds which exhibit ...
Rhodium(III) catalyzed synthesis of isoquinolone fused azabicycles through C-H activation of N-pivaloyloxy benzamides

Praveen, P; Jijy, E; Aparna, P S; Viji, S; Radhakrishnan, K V (Elsevier, 2014)

Herein we describe an efficient one pot strategy toward highly functionalized isoquinolone fused azabicycles having great synthetic potential via C-H activation of N-pivaloyloxy benzamides under very mild conditions. The ...
Ruthenium catalyzed desymmetrization of diazabicyclic olefins to access heteroaryl substituted cyclopentenes through C-H activation of phenylazoles

Aparna, P S; Prabha, B; Praveen, P; Jijy, E; Luxmi Varma, R; Radhakrishnan, K V (Elsevier Science, 2014)

The first ruthenium catalyzed redox-neutral C-H activation strategy for the ring-opening of diazabicyclic olefins via C-H bond cleavage of phenyl azoles is reported. The developed method offers a novel route to functionalized ...

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