DSpace Home
→
Browsing by Subject

Browsing by Subject "Rhodium"

Now showing items 1-4 of 4

Molecular electrostatic potential approach to determining the steric effect of phosphine ligands in organometallic chemistry

Suresh, C H (American Chemical Society, 2006)

A two-layer ONIOM(B3LYP/6-31G(d, p): UFF) quantum mechanics (QM) -molecular mechanics ( MM) optimization of PR3 ligands, where the QM layer is always constructed as PH3, followed by molecular electrostatic potential ( MESP) ...
Quantitative assessment of the stereoelectronic profile of phosphine ligands

Jomon Mathew; Tinto Thomas; Suresh, C H (American Chemical Society, 2007)

The stereoelectronic profile of a variety of phosphine ligands (PR3) have been estimated using a combined approach of quantum mechanics (QM) and molecular mechanics (MM). The quantum mechanically derived molecular electrostatic ...
Rhodium(III) catalyzed synthesis of isoquinolone fused azabicycles through C-H activation of N-pivaloyloxy benzamides

Praveen, P; Jijy, E; Aparna, P S; Viji, S; Radhakrishnan, K V (Elsevier, 2014)

Herein we describe an efficient one pot strategy toward highly functionalized isoquinolone fused azabicycles having great synthetic potential via C-H activation of N-pivaloyloxy benzamides under very mild conditions. The ...
Rhodium(III)-catalyzed C-H activation of phenylazoles toward C-N bond cleavage of diazabicyclic olefins: A facile access to mono- and biscyclopentenyl-functionalized aza-heteroaromatics

Praveen, P; Aparna, P S; Jijy, E; Santhini, P V; Sunil Varughese; Radhakrishnan, K V (Georg Thieme Verlag, 2014)

A [RhCl2Cp*](2)-catalyzed stereoselective C-N bond cleavage of diazabicyclic olefins via C-H activation of phenylazoles in the presence of an acetate source is described. The developed method provides an easy access to ...

Now showing items 1-4 of 4

Search DSpace

Advanced Search

Browse

All of DSpace

Browsing by Subject "Rhodium"

Browsing by Subject "Rhodium"

Search DSpace

Browse

All of DSpace

My Account