Selective recognition of tryptophan through inhibition of intramolecular charge-transfer interactions in an aqueous medium

dc.contributor.author	Mahesh Hariharan
dc.contributor.author	Suneesh, C K
dc.contributor.author	Ramaiah, D
dc.date.accessioned	2014-05-26T11:03:23Z
dc.date.available	2014-05-26T11:03:23Z
dc.date.issued	2007
dc.identifier.citation	Organic Letters 9(3):417-420;1 Feb 2007	en_US
dc.identifier.issn	1523-7060
dc.identifier.uri	http://ir.niist.res.in:8080/jspui/handle/123456789/1464
dc.description.abstract	A novel donor-acceptor conjugate 1 was synthesized, and its interactions with various amino acids have been investigated as compared to the model system 2. The conjugate 1 unusually forms an intramolecular charge-transfer complex in the aqueous medium and undergoes selective binding interactions with tryptophan. The uniqueness of this system is that it selectively recognizes tryptophan among all other amino acids and involves synergistic effects of pi-stacking, electrostatic, and donor-acceptor interactions	en_US
dc.language.iso	en	en_US
dc.publisher	American Chemical Society	en_US
dc.subject	Viologen-linked acridines	en_US
dc.subject	Amino acids	en_US
dc.subject	Molecular recognition	en_US
dc.subject	Supramolecular chemistry	en_US
dc.subject	Electron transfer	en_US
dc.subject	Macrocyclic host	en_US
dc.subject	Receptors	en_US
dc.subject	DNA	en_US
dc.title	Selective recognition of tryptophan through inhibition of intramolecular charge-transfer interactions in an aqueous medium	en_US
dc.type	Article	en_US
niist.citation