Bis-functionalization of 1,3-dienes through 1,4-conjugate addition of amphiphilic bis-pi-allyl and related palladium intermediates

dc.contributor.author	Baiju, T V
dc.contributor.author	Ajesh, V
dc.contributor.author	Nayana Joseph
dc.contributor.author	Preethanuj, P
dc.contributor.author	Radhakrishnan, K V
dc.contributor.author	Suresh, E
dc.contributor.author	Yamamoto, Y
dc.date.accessioned	2014-06-11T04:28:36Z
dc.date.available	2014-06-11T04:28:36Z
dc.date.issued	2014
dc.identifier.citation	Synlett 25(3):359-364;13 Feb 2014	en_US
dc.identifier.issn	0936-5214
dc.identifier.uri	http://ir.niist.res.in:8080/jspui/handle/123456789/1510
dc.description.abstract	Palladium-catalyzed three-component coupling of allylstannane, allyl chloride and a functionalized diene is described. Regioselective 1,4-functionalization of the Michael acceptor 1,3-diene is accomplished by the amphiphilic bis--allylpalladium complex. To the best of our knowledge, this is the first time a functionalized 1,3-butadiene has been used as a Michael acceptor. The scope of the present strategy is further extended to 1,4-allylation-oxyallylation of functionalized dienes.	en_US
dc.language.iso	en	en_US
dc.publisher	Georg Thieme Verlag	en_US
dc.subject	Palladium	en_US
dc.subject	Allylation	en_US
dc.subject	Allyl complexes	en_US
dc.subject	Michael addition	en_US
dc.title	Bis-functionalization of 1,3-dienes through 1,4-conjugate addition of amphiphilic bis-pi-allyl and related palladium intermediates	en_US
dc.type	Article	en_US